---
experiment:
    id: '77'
    experiment_category:
        - 'Gas phase chemical reaction'
    experiment_date: '2005-02-11'
    temperature: '25'
    relative_humidity: ''
    seeded_experiment: ''
    type_of_seed: ''
    seed_concentration_units: ''
    initial_seed_concentration_value: ''
    fuchs_adjusted_surface_area: ''
    reaction_type:
        - 'Photooxidation'
    oxidant_name: 'Chlorine radical'
    ro2_main_fate: 'Not Sure'
    ro2_lifetime_seconds: ''
    experiment_goals: 'Determine products of ethyl formate oxidation in the atmosphere.  Specifically, investigate atmospheric fate of HC(O)OCH(O.)CH3 radical.'
    experiment_summary: 'Photolyze Cl2/ethyl formate/O2 /N2 mixture.  Follow loss of ethyl formate and formation of products'
    additional_notes: '150 Torr O2, 298 K'
    light_flux_characterization_id: ''
    particle_loss_characterization_id: ''
    vapor_loss_characterization_id: ''
    data_file_original_name: 'timeline_esters1.csv'
    oxidant_concentration_units: 'parts_per_million'
    initial_oxidant_concentration_value: 'Cl2 concentration 141.5'
    reactants:
        -
            is_aerosol: ''
            pubchem_cid: '8025'
            reactant_name: 'ETHYL FORMATE'
            functional_group:
                - 'Ester'
            concentration_units: 'parts_per_million'
            functional_group_other: ''
            initial_concentration_value: '8.49'
    skip_headers_timeline: ''
    condensation_sink_rate_coefficient: ''
    is_draft: ''
    pressure: '750 Torr'
    doi: 'https://doi.org/10.5065/xs90-vs66'
    download_file_path: 'experiments/EXP_77.zip'
    experiment_link: 'https://icarus.ucdavis.edu/experiment/77'
    experiment_set_name: 'Ethyl formate Oxidation versus Temperature and O2 Partial Pressure'
    experiment_set_link: 'https://icarus.ucdavis.edu/experimentset/147'
    chamber_link: 'https://icarus.ucdavis.edu/chamber/529'
    chamber_name: 'NCAR First Floor Stainless Steel'
    experiment_name: 'NCAR_20050211_ETHYL FORMATE_Chlorine radical_No Seed_Cl2 / Ethyl formate photooxidation, 298 K, 150 Torr O2'
    experiment_created_at: '2019-08-20 09:56:41'
    experiment_updated_at: '2023-08-22 00:50:13'
chamber:
    id: '529'
    name: 'NCAR First Floor Stainless Steel'
    chamber_flow_mode: 'Batch'
    chamber_shape: ''
    chamber_volume_in_cubic_meters: '0.047'
    chamber_surface_area_in_square_meters: '1.15'
    flow_through_rate_in_liters_per_minute: ''
    chamber_body_material: 'Stainless Steel'
    chamber_body_thickness_in_mils: ''
    bag_replacement_date: ''
    bag_replacement_frequency: ''
    chamber_cleaning_method:
        - 'evacuation'
    o3_background: ''
    nox_background: ''
    particle_background: ''
    air_filtration_method: ''
    mixing_fans: ''
    mixing_fan_material: ''
    temperature_control: '1'
    temperature_measurements_recorded: '1'
    temperature_range_min_degrees_celsius: '-50'
    temperature_range_max_degrees_celsius: '70'
    humidity_control: ''
    humidity_measurements_recorded: ''
    relative_humidity_range_min_percent: ''
    relative_humidity_range_max_percent: ''
    particle_experiment_capability: ''
    lights: '1'
    light_source_type: '["Xenon Arc Lamps"]'
    link_to_supplemental_information: ''
    additional_notes: ''
    organization_id: '541'
    created_at: '2019-07-22T22:36:41.000000Z'
    updated_at: '2020-02-20T23:40:38.000000Z'
experimentSet:
    id: '147'
    name: 'Ethyl formate Oxidation versus Temperature and O2 Partial Pressure'
    experiment_set_description: 'Ethyl formate Oxidation versus Temperature and O2 Partial Pressure'
    chamber_id: '529'
    created_at: '2019-07-24T15:49:33.000000Z'
    updated_at: '2023-08-22T07:51:50.000000Z'
    time_units: ''
    publications: []
    downloadFileSize: '201418'
    download_file_path: 'experimentSets/EXPSET_147.zip'
    collaborators: []
organization:
    id: '541'
    lab_name: 'NCAR'
    lab_affiliation: 'NCAR ACOM Boulder CO USA'
    lab_currently_active: '1'
    legal_constraints_statement: 'The Principal Investigator (PI) and institution retain any and all rights to the data that they generated. Use of ICARUS shared data in published materials or materials under review, including peer-reviewed publications or submissions, conference presentations, reports, and proposals, requires notification of the PI. For materials meant for dissemination that significantly depend on the data shared by specific PIs, the database user is required to offer the specific PI(s), and associated coworkers, co-authorship in said publications. When ICARUS data are used in published materials, the data should be cited and the DOI for the Experiment or Experiment Set should be provided in the Data Availability statement.'
    access_constraints_statement: 'These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.'
    additional_notes: ''
    created_at: '2019-07-22T22:22:03.000000Z'
    updated_at: '2019-07-24T15:41:56.000000Z'
    pi:
        -
            name_first: 'John'
            name_middle: ''
            name_last: 'Orlando'
            orcid: ''
            phone: '303 497 1486'
            email: 'orlando@ucar.edu'
    data_manager:
        -
            name_first: 'Geoff Tyndall'
            name_middle: ''
            name_last: ''
            phone: '303 497 1472'
            email: 'tyndall@ucar.edu'

---
Time (min),Action
0,"Fill chamber (O2, Cl2, Ethyl formate, N2)"
10,Record FTIR spectrum
13.5,photolyze chamber contents
15,"block lamp, record FTIR spectrum"
19.5,photolyze chamber contents
21,"block lamp, record FTIR spectrum"
28.5,photolyze chamber contents
30,"block lamp, record FTIR spectrum"
39,photolyze chamber contents
41,"block lamp, record FTIR spectrum"
47,photolyze chamber contents
49,"block lamp, record FTIR spectrum"