---
instrument_id: '503'
data_file_original_name: 'E5_CIMS.csv'
skip_headers: '1'
charts: ''
headers:
    - 'tlocal_CIMS'
    - 'C10H30O5Si5_ppb'
    - 'C9H28O6Si5_ppb'
    - 'C10H28O7Si5_ppb'
    - 'C10H30O8Si5_ppb'
dataset_id: '4544'
experiment_link: 'https://icarus.ucdavis.edu/chambers/569/experiments/932'
experiment_set_link: 'https://icarus.ucdavis.edu/chambers/569/experimentSets/270'
chamber_link: 'https://icarus.ucdavis.edu/chambers/569'
dataset_created_at: '2025-05-29 14:49:52'
dataset_updated_at: '2025-05-29 14:49:52'
instrument_link: 'https://icarus.ucdavis.edu/chambers/569/instruments/503'
instrument:
    id: '503'
    short_name: 'Toluene CIMS'
    full_name: 'Atmospheric pressure interface toluene chemical ionization mass spectrometer'
    manufacturer: 'Tofwerk/Aerodyne'
    model: 'APi-LTOF-CIMS'
    year: '2016'
    data_recording_software: 'Tofwerk''s TOFDAQ'
    data_analysis_software: 'Tofwerk''s TofWare and further processing with Igor scripts'
    raw_data_time_resolution: '1 Hz'
    analysis_data_averaging: 'Data is averaged to 1 minute resolution offline.'
    detection_limit: '3x the standard deviation of the noise'
    quantification_limit: ''
    sensitivity_to_temperature: ''
    sensitivity_to_relative_humidity: ''
    sampling_method: 'Direct sampling with teflon tubing'
    sample_preparation_method: 'No sample preparation'
    sample_residence_time_in_seconds: ''
    length_of_tubing_in_cm: '100'
    flow_rate: '1.7 slpm'
    tubing_material: 'PFA Teflon'
    chemical_identification_method: 'm/z values are assigned chemical formulas based on high-resolution peak fitting with constrained isotopes. The identities of the chemicals are determined from what elements are expected to be present and how well the predicted isotopes match the measured distribution.'
    data_analysis_method: ''
    quantification_method: ''
    calibration_method: 'Calibration of D5 was performed using a permeation tube that is held at a constant temperature. The permeation rate is determined using gravimetric analysis and the dilution is calibrated with primary flow standards. The mixing ratio in ppb is then calculated from the dilution ratios and flows into the instrument.'
    calibration_drift_estimate: ''
    calibration_schedule: 'As Needed'
    uncertainty_estimation_method: 'Uncertainty should follow counting error statistics when units are report in normalized counts per second unless otherwise specified. For calibrated compounds, uncertainty in the calibration is included via error propagation.'
    known_interferences: ''
    link_to_supplemental_information: 'This is the same instrument as the Browne Lab CIMS (https://icarus.ucdavis.edu/instruments/503?organization=562)'
    additional_notes: "Calibration factor for D5: 1065 ncps/ppb\r\nCalibration factor for D5 oxidation producuts: 431 ncps/ppb"
    organization_id: '562'
    created_at: '2022-01-28T00:31:24.000000Z'
    updated_at: '2025-05-29T21:21:05.000000Z'
    column_descriptors: "C10H30O5Si5 = D5\r\nC9H28O6Si5 = siloxanol\r\nC10H28O7Si5 = formate ester\r\nC10H30O8Si5 = ether hydroperoxide or trioxide"
    sampling_protocol: 'Online'
    skip_headers: '1'
    tubing_inner_diameter: '3/16 in'
    what_is_measured: 'Gas-phase siloxanes and oxidation products'
    measurement_uncertainty: 'Measurements have uncertainties equal to the square root of the counted ions, according to Poisson statistics.'
    measurement_units: '(a) time (local) (b) ppb'

---
tlocal_CIMS,C10H30O5Si5_ppb,C9H28O6Si5_ppb,C10H28O7Si5_ppb,C10H30O8Si5_ppb
7/8/2024 12:14:19,0.318355,,0.00173828,0
7/8/2024 12:15:19,0.321161,,0.000420481,0
7/8/2024 12:16:19,0.312666,,5.32143e-05,0
7/8/2024 12:17:19,0.308205,,0.000888592,0
7/8/2024 12:18:19,0.31095,,0.00137164,0.000157491
7/8/2024 12:19:19,0.304973,,0.000510323,0
7/8/2024 12:20:19,0.308801,,0.00122202,0
7/8/2024 12:21:19,0.309043,,0.0015076,0
7/8/2024 12:22:19,0.312434,,0.000844771,0
7/8/2024 12:23:19,0.309909,,0.000858385,0
7/8/2024 12:24:19,0.311162,,0.000441744,0
7/8/2024 12:25:19,0.311351,,0.00044469,0
7/8/2024 12:26:19,0.304818,,0.00092394,0
7/8/2024 12:27:19,0.303312,,0.000702142,0
7/8/2024 12:28:19,0.303107,,0.00124785,0
7/8/2024 12:29:18,0.286177,,0.00227314,0.00103373
7/8/2024 12:30:18,0.181577,,0.00728619,0.000829013
7/8/2024 12:31:18,0.18091,,0.00783212,0.000787964
7/8/2024 12:32:18,0.183969,,0.00972091,0.000517802
7/8/2024 12:33:18,0.185854,,0.00842628,0.000278871
7/8/2024 12:34:18,0.184923,,0.00813369,0
7/8/2024 12:35:18,0.185598,,0.00679047,0.000482326
7/8/2024 12:36:18,0.186424,,0.0083727,0.000766913
7/8/2024 12:37:18,0.187225,,0.0049952,0
7/8/2024 12:38:18,0.188771,,0.00641129,0.000756398
7/8/2024 12:39:18,0.185229,,0.00755822,0.00113064
7/8/2024 12:40:18,0.186528,,0.00339923,0.00103614
7/8/2024 12:41:18,0.189051,,0.00320355,0.000153476
7/8/2024 12:42:18,0.187206,,0.00286038,0
7/8/2024 12:43:18,0.186498,,0.00411064,0
7/8/2024 12:44:18,0.186969,,0.00402243,0.000271945
7/8/2024 12:45:18,0.186609,,0.00324173,0
7/8/2024 12:46:17,0.185588,,0.00373055,0.000698496
7/8/2024 12:47:17,0.184953,,0.00296027,0
7/8/2024 12:48:17,0.184786,,0.00268987,0
7/8/2024 12:49:17,0.183511,,0.00193506,0
7/8/2024 12:50:17,0.183352,,0.00200876,3.27784e-05
7/8/2024 12:51:17,0.18441,,0.00442214,0.00114594
7/8/2024 12:52:17,0.183928,,0.00156079,0
7/8/2024 12:53:17,0.18262,,0.00279298,0
7/8/2024 12:54:17,0.184019,,0.00306405,0
7/8/2024 12:55:17,0.18157,,0.000985608,0.000874034
7/8/2024 12:56:17,0.18248,,0.00294671,7.47523e-05
7/8/2024 12:57:17,0.181283,,0.00126303,0
7/8/2024 12:58:17,0.181482,,0.0020528,0
7/8/2024 12:59:17,0.181793,,0.00119346,0.00015283
7/8/2024 13:00:17,0.181349,,0.000649103,0.000265659
7/8/2024 13:01:17,0.181435,,0.0011367,0
7/8/2024 13:02:17,0.183545,,0.00176975,0.000826433
7/8/2024 13:03:16,0.182573,,0.00171014,0
7/8/2024 13:04:16,0.181295,,0.00168455,0.000316179
7/8/2024 13:05:16,0.182543,,0.00143667,0.000309254
7/8/2024 13:06:16,0.183103,,0.00102866,0
7/8/2024 13:07:16,0.181905,,0.00163316,0
7/8/2024 13:08:16,0.182641,,0.00116867,0
7/8/2024 13:09:16,0.181095,,0.00157428,3.68201e-05
7/8/2024 13:10:16,0.181301,,0.00196836,0.000118883
7/8/2024 13:11:16,0.181357,,0.00231161,0
7/8/2024 13:12:16,0.180888,,0.00211732,0
7/8/2024 13:13:16,0.180911,,0.000826673,0
7/8/2024 13:14:18,0.18198,,0.00129214,3.21042e-05
7/8/2024 13:15:18,0.181738,,0.000494131,0.000782096
7/8/2024 13:16:18,0.181507,,0.00167471,0.000155452
7/8/2024 13:17:18,0.182526,,0.000698574,0.000146324
7/8/2024 13:18:18,0.180891,,0.0016742,0
7/8/2024 13:19:17,0.180953,,0.00153167,0
7/8/2024 13:20:17,0.182056,,0.00108703,0.000439625
7/8/2024 13:21:17,0.182117,,0.000853872,0.000415089
7/8/2024 13:22:17,0.181709,,0.00223101,0
7/8/2024 13:23:17,0.1819,,0.000802997,0.000372569
7/8/2024 13:24:17,0.182086,,0.000332623,0
7/8/2024 13:25:17,0.18114,,0.00133735,4.78262e-05
7/8/2024 13:26:17,0.181076,,0.00140143,0
7/8/2024 13:27:17,0.181739,,0,0
7/8/2024 13:28:17,0.180929,,0.00160658,0
7/8/2024 13:29:17,0.180033,,0.000969301,0.000265489
7/8/2024 13:30:17,0.180918,,0.000613282,0
7/8/2024 13:31:17,0.180166,,0.000304991,0
7/8/2024 13:32:17,0.179897,,0.000539739,0
7/8/2024 13:33:17,0.181646,,0.00139403,0
7/8/2024 13:34:17,0.180485,,0.0009185,0
7/8/2024 13:35:16,0.180557,,0.000763216,0.00118907
7/8/2024 13:36:16,0.183448,,0.00124015,0.000674188
7/8/2024 13:37:16,8.2138,,0.00135264,0
7/8/2024 13:38:16,70.2042,,0.00167809,0
7/8/2024 13:39:16,71.4028,,0,0
7/8/2024 13:40:16,71.516,,0.000985153,0
7/8/2024 13:41:16,71.3665,,0.000324808,0
7/8/2024 13:42:16,70.7522,,0,0
7/8/2024 13:43:16,70.6875,,0.0012142,0
7/8/2024 13:44:16,70.7853,,0.000190041,0
7/8/2024 13:45:16,69.9843,,0.00135441,0
7/8/2024 13:46:16,69.5908,,0.000583508,0
7/8/2024 13:47:16,69.8035,,0,0
7/8/2024 13:48:16,70.1359,,0.000957314,0
7/8/2024 13:49:16,69.553,,0.00551373,0
7/8/2024 13:50:16,69.2489,,0.00600247,0
7/8/2024 13:51:16,68.0872,,0.0134964,0
7/8/2024 13:52:15,65.4859,,0.0296763,0
7/8/2024 13:53:15,64.1523,,0.035992,0
7/8/2024 13:54:15,62.6898,,0.035026,0
7/8/2024 13:55:15,61.3825,,0.0284481,0
7/8/2024 13:56:15,61.7009,,0.0355941,0
7/8/2024 13:57:15,60.6545,,0.0383691,0
7/8/2024 13:58:15,59.1614,,0.0334991,0
7/8/2024 13:59:15,57.8763,,0.0296456,0
7/8/2024 14:00:15,56.4489,,0.0274045,0
7/8/2024 14:01:15,55.4388,,0.0275535,0
7/8/2024 14:02:15,54.3526,,0.0228606,0
7/8/2024 14:03:15,52.9214,,0.0207262,0
7/8/2024 14:04:15,52.1878,,0.0161496,0
7/8/2024 14:05:15,51.9349,,0.0180277,0
7/8/2024 14:06:15,50.9535,,0.0165878,0
7/8/2024 14:07:15,51.1895,,0.0146962,0
7/8/2024 14:08:15,51.5857,,0.0143342,0
7/8/2024 14:09:14,51.3626,,0.0127694,0
7/8/2024 14:10:14,51.7114,,0.0128772,0
7/8/2024 14:11:14,51.9622,,0.0121495,0
7/8/2024 14:12:14,51.5679,,0.0107109,0
7/8/2024 14:13:14,52.2213,,0.0101714,0
7/8/2024 14:14:16,52.7524,,0.00872412,0
7/8/2024 14:15:16,52.8623,0.0811171,0.00970335,0
7/8/2024 14:16:16,53.3891,-0.0340899,0.00749206,0
7/8/2024 14:17:16,53.4778,0.0184842,0.00888585,0
7/8/2024 14:18:16,53.2745,0.134041,0.0101449,0
7/8/2024 14:19:16,54.0236,-0.13872,0.00766896,0
7/8/2024 14:20:16,54.2476,-0.0501245,0.00692304,0
7/8/2024 14:21:16,54.6917,-0.150449,0.0101248,0
7/8/2024 14:22:16,54.3869,0.116651,0.00827972,0
7/8/2024 14:23:16,54.6039,0.0776522,0.00790424,0
7/8/2024 14:24:16,54.6801,0.0899168,0.00896798,0
7/8/2024 14:25:15,55.029,-0.0758429,0.00856772,0
7/8/2024 14:26:15,55.3541,-0.228858,0.00522185,0
7/8/2024 14:27:15,54.5257,0.303925,0.00717786,0
7/8/2024 14:28:15,55.1575,-0.0318881,0.00464212,0
7/8/2024 14:29:15,55.1681,0.161346,0.00670717,0
7/8/2024 14:30:15,55.4223,-0.0997542,0.0081271,0
7/8/2024 14:31:15,55.6838,-0.259379,0.00551041,0
7/8/2024 14:32:15,55.6875,-0.178037,0.00597402,0
7/8/2024 14:33:15,55.5399,-0.0700898,0.00642482,0
7/8/2024 14:34:15,55.5643,-0.0668895,0.00379849,0
7/8/2024 14:35:15,55.9456,-0.144782,0.0069533,0
7/8/2024 14:36:15,55.6873,0.0635221,0.00568926,0
7/8/2024 14:37:15,55.384,0.221628,0.00771076,0
7/8/2024 14:38:15,55.6331,0.00192692,0.00478076,0
7/8/2024 14:39:15,56.3133,-0.239435,0.0080215,0
7/8/2024 14:40:15,55.6785,0.315099,0.00783705,0
7/8/2024 14:41:14,55.7763,0.237988,0.00334597,0
7/8/2024 14:42:14,55.9877,0.0282662,0.00479216,0
7/8/2024 14:43:14,55.63,0.122069,0.00354875,0
7/8/2024 14:44:14,56.0797,-0.181384,0.00800208,0
7/8/2024 14:45:14,55.8034,-0.120195,0.00343345,0
7/8/2024 14:46:14,55.2063,0.451639,0.00526276,0
7/8/2024 14:47:14,55.9882,0.0102011,0.00467522,0
7/8/2024 14:48:14,55.3933,0.241861,0.00813882,0
7/8/2024 14:49:14,55.3654,0.10438,0.0175737,0.00213314
7/8/2024 14:50:14,55.3441,0.383218,0.0319489,0.00435394
7/8/2024 14:51:14,55.7584,0.145209,0.0382255,0.00818419
7/8/2024 14:52:14,55.9282,0.269118,0.0509069,0.016996
7/8/2024 14:53:14,55.5221,0.359417,0.0581536,0.0166702
7/8/2024 14:54:14,55.5217,0.497653,0.0706841,0.0204534
7/8/2024 14:55:14,56.5689,0.107236,0.0847745,0.0288668
7/8/2024 14:56:14,56.2744,0.361164,0.102314,0.028116
7/8/2024 14:57:14,56.4312,0.404427,0.102931,0.0353252
7/8/2024 14:58:13,56.7365,0.566688,0.11178,0.037121
7/8/2024 14:59:13,56.6129,0.668649,0.124564,0.0446507
7/8/2024 15:00:13,57.0285,0.619876,0.15648,0.0484303
7/8/2024 15:01:13,56.6966,0.935326,0.159246,0.0543451
7/8/2024 15:02:13,56.3497,0.959238,0.183938,0.0550224
7/8/2024 15:03:13,56.1902,1.03903,0.190024,0.0586937
7/8/2024 15:04:13,56.1186,0.89083,0.212865,0.0728884
7/8/2024 15:05:13,56.2141,0.994304,0.233162,0.0700806
7/8/2024 15:06:13,55.7835,1.22021,0.244263,0.0748501
7/8/2024 15:07:13,55.4638,1.28753,0.25549,0.0784975
7/8/2024 15:08:13,55.3968,1.29656,0.278793,0.0851863
7/8/2024 15:09:13,55.2904,1.47432,0.314102,0.0801781
7/8/2024 15:10:13,55.378,1.35172,0.325316,0.0874641
7/8/2024 15:11:13,54.8925,1.58097,0.334265,0.0879875
7/8/2024 15:12:13,54.5777,1.67754,0.366504,0.0961524
7/8/2024 15:13:13,55.1365,1.32174,0.385333,0.10742
7/8/2024 15:14:14,54.7019,1.87202,0.400541,0.102432
7/8/2024 15:15:14,54.8084,1.78819,0.436261,0.110381
7/8/2024 15:16:14,54.5799,2.28376,0.426819,0.115249
7/8/2024 15:17:14,55.0734,2.18675,0.44405,0.116424
7/8/2024 15:18:14,55.5721,2.25511,0.481748,0.129328
7/8/2024 15:19:14,56.3414,2.00813,0.540921,0.131328
7/8/2024 15:20:14,55.9078,2.39444,0.567471,0.123816
7/8/2024 15:21:14,56.2953,2.28613,0.620709,0.129344
7/8/2024 15:22:14,56.4148,2.32249,0.629338,0.136725
7/8/2024 15:23:14,56.3447,2.53231,0.649508,0.137309
7/8/2024 15:24:14,56.3314,2.68909,0.669608,0.143057
7/8/2024 15:25:14,56.8453,2.6562,0.720522,0.155361
7/8/2024 15:26:14,56.3749,3.2038,0.77976,0.154627
7/8/2024 15:27:14,56.6997,2.90341,0.810075,0.139889
7/8/2024 15:28:14,57.0528,2.69121,0.85673,0.142002
7/8/2024 15:29:14,56.9507,2.97358,0.904413,0.141055
7/8/2024 15:30:14,56.743,3.28219,0.893756,0.13781
7/8/2024 15:31:13,57.0117,3.36136,0.940923,0.149639
7/8/2024 15:32:13,56.4076,3.65681,0.963801,0.143977
7/8/2024 15:33:13,56.1991,3.64917,0.97138,0.163297
7/8/2024 15:34:13,56.4389,3.32314,1.06619,0.149429
7/8/2024 15:35:13,55.9437,3.44645,1.08375,0.163448
7/8/2024 15:36:13,55.6165,3.54089,1.08965,0.145489
7/8/2024 15:37:13,54.9563,3.9174,1.09398,0.162317
7/8/2024 15:38:13,55.0178,4.01337,1.15079,0.155097
7/8/2024 15:39:13,54.956,3.86055,1.17765,0.16301
7/8/2024 15:40:13,54.9233,3.96415,1.23014,0.168228
7/8/2024 15:41:13,55.0418,3.97512,1.26207,0.161761
7/8/2024 15:42:13,54.7174,4.18618,1.27789,0.164483
7/8/2024 15:43:13,54.447,4.30079,1.28816,0.16154
7/8/2024 15:44:13,54.0733,4.71112,1.27324,0.164228
7/8/2024 15:45:13,55.2442,4.361,1.38466,0.178934
7/8/2024 15:46:13,56.0354,4.00819,1.50908,0.184751
7/8/2024 15:47:12,55.7146,4.73718,1.47063,0.17931
7/8/2024 15:48:12,56.0861,4.61397,1.52026,0.179284
7/8/2024 15:49:12,55.8523,4.90124,1.5329,0.197967
7/8/2024 15:50:12,55.9344,4.90294,1.58306,0.201704
7/8/2024 15:51:12,56.2792,4.95943,1.61719,0.193751
7/8/2024 15:52:12,56.7161,4.88572,1.67467,0.193555
7/8/2024 15:53:12,56.5253,5.15872,1.71256,0.197277
7/8/2024 15:54:12,56.4174,5.14222,1.76203,0.200698
7/8/2024 15:55:12,56.4489,5.32829,1.8258,0.1792
7/8/2024 15:56:12,56.3611,5.5555,1.87217,0.179346
7/8/2024 15:57:12,56.9177,5.14338,1.94622,0.180372
7/8/2024 15:58:12,56.6352,5.29938,1.91584,0.183349
7/8/2024 15:59:12,56.6763,5.58509,1.96089,0.208729
7/8/2024 16:00:12,56.3748,5.77327,2.01841,0.193794
7/8/2024 16:01:12,56.5163,5.66586,2.08287,0.186848
7/8/2024 16:02:12,55.7249,6.00108,2.05494,0.174039
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7/8/2024 16:06:11,54.9022,6.36373,2.16945,0.202776
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7/8/2024 16:18:13,55.8477,7.35909,2.73194,0.175654
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7/8/2024 16:20:12,55.4272,7.75853,2.80865,0.178105
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7/8/2024 16:22:12,56.9419,7.53074,3.00815,0.200114
7/8/2024 16:23:12,57.0416,7.76791,3.04036,0.19566
7/8/2024 16:24:12,56.5943,7.97812,3.05793,0.191107
7/8/2024 16:25:12,57.0975,7.79475,3.15495,0.199959
7/8/2024 16:26:12,56.8572,8.19972,3.16232,0.198758
7/8/2024 16:27:12,56.9196,8.04629,3.17953,0.19378
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7/8/2024 16:31:12,56.7269,8.60171,3.38106,0.186422
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7/8/2024 16:33:12,56.2947,8.6408,3.47745,0.203697
7/8/2024 16:34:12,55.4253,9.18457,3.40863,0.187413
7/8/2024 16:35:12,56.0101,8.71107,3.54844,0.195444
7/8/2024 16:36:11,55.8159,8.72068,3.55762,0.201275
7/8/2024 16:37:11,55.1403,9.24834,3.4962,0.183435
7/8/2024 16:38:11,54.6216,9.47105,3.54175,0.183494
7/8/2024 16:39:11,55.368,8.98946,3.64907,0.201968
7/8/2024 16:40:11,55.4488,8.98314,3.70799,0.190405
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7/8/2024 16:47:11,55.9753,10.1654,4.05038,0.200609
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7/8/2024 16:49:11,56.3273,10.1018,4.14868,0.199054
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7/8/2024 16:52:10,56.0566,10.3149,4.08759,0.211574
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7/8/2024 16:57:10,56.2829,9.94129,4.14056,0.2106
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7/8/2024 16:59:10,56.441,9.81635,4.14125,0.177674
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7/8/2024 17:02:10,55.3217,10.4377,4.04256,0.167804
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7/8/2024 17:11:09,54.9743,10.2079,4.06515,0.164257
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