---
instrument_id: '503'
data_file_original_name: 'D5Cl2_20210325.csv'
skip_headers: '1'
charts: ''
headers:
    - 'Time'
    - '''(C9H28O6Si5)H+'''
    - '''(C8H26O7Si5)H+'''
    - '''(C10H28O7Si5)H+'''
    - '''(C9H26O8Si5)H+'''
    - '''(C2H6OSi)5O2H+'''
    - '''(C2H6OSi)5O3H+'''
    - '''(C10H29O5Si5NO3)H+'''
    - '''(C10H29O5Si5NO4)H+'''
    - '(C2H6OSi)5H+'
dataset_id: '3978'
experiment_link: 'https://icarus.ucdavis.edu/chambers/559/experiments/759'
experiment_set_link: 'https://icarus.ucdavis.edu/chambers/559/experimentSets/244'
chamber_link: 'https://icarus.ucdavis.edu/chambers/559'
dataset_created_at: '2022-01-28 16:15:25'
dataset_updated_at: '2022-01-28 16:15:25'
instrument_link: 'https://icarus.ucdavis.edu/chambers/559/instruments/503'
instrument:
    id: '503'
    short_name: 'Toluene CIMS'
    full_name: 'Atmospheric pressure interface toluene chemical ionization mass spectrometer'
    manufacturer: 'Tofwerk/Aerodyne'
    model: 'APi-LTOF-CIMS'
    year: '2016'
    data_recording_software: 'Tofwerk''s TOFDAQ'
    data_analysis_software: 'Tofwerk''s TofWare and further processing with Igor scripts'
    raw_data_time_resolution: '1 Hz'
    analysis_data_averaging: 'Data is averaged to 1 minute resolution offline.'
    detection_limit: '3x the standard deviation of the noise'
    quantification_limit: ''
    sensitivity_to_temperature: ''
    sensitivity_to_relative_humidity: ''
    sampling_method: 'Direct sampling with teflon tubing'
    sample_preparation_method: 'No sample preparation'
    sample_residence_time_in_seconds: ''
    length_of_tubing_in_cm: '1000'
    flow_rate: '1.7 slpm'
    tubing_material: 'PFA Teflon'
    chemical_identification_method: 'm/z values are assigned chemical formulas based on high-resolution peak fitting with constrained isotopes. The identities of the chemicals are determined from what elements are expected to be present and how well the predicted isotopes match the measured distribution.'
    data_analysis_method: ''
    quantification_method: ''
    calibration_method: ''
    calibration_drift_estimate: ''
    calibration_schedule: ''
    uncertainty_estimation_method: 'Uncertainty should follow counting error statistics when units are report in normalized counts per second unless otherwise specified. For calibrated compounds, uncertainty in the calibration is included via error propagation.'
    known_interferences: ''
    link_to_supplemental_information: ''
    additional_notes: ''
    organization_id: '562'
    created_at: '2022-01-28T00:31:24.000000Z'
    updated_at: '2022-01-28T23:56:14.000000Z'
    column_descriptors: ''
    sampling_protocol: 'Online'
    skip_headers: '1'
    tubing_inner_diameter: '3/16 in'
    what_is_measured: 'Gas-phase siloxanes and oxidation products'
    measurement_uncertainty: 'Measurements have uncertainties equal to the square root of the counted ions, according to Poisson statistics.'
    measurement_units: 'Normalized counts per second'

---
Time,'(C9H28O6Si5)H+','(C8H26O7Si5)H+','(C10H28O7Si5)H+','(C9H26O8Si5)H+','(C2H6OSi)5O2H+','(C2H6OSi)5O3H+','(C10H29O5Si5NO3)H+','(C10H29O5Si5NO4)H+',(C2H6OSi)5H+
3699530246,5.41568466,11.73286278,0.323113842,0,0.399541122,0.099557892,0,1.69580241,273.39508
3699530306,10.08072342,11.56841892,0.285778782,0.032798578,0.350838216,0.324841266,0.139701368,2.77380432,253.01738
3699530367,8.16063174,11.90629242,0.303817176,0.230183226,0.28503765,0.058100872,0.25139808,1.634476266,235.37556
3699530427,5.90913522,12.38579244,0.155981264,0,0.439523352,0.531028458,0,1.187738154,220.00261
3699530487,3.4873272,13.30949196,0.217052586,0.039863345,0.37814364,0.025563577,0,1.36596429,203.37013
3699530547,6.72272136,13.25838654,0.236003148,0.004336236,0.483791274,0.283407246,0,1.99573308,193.93683
3699530607,4.2241608,13.29575994,0.185414832,0.203387616,0.480877542,0.131355139,0,0.900627858,238.82967
3699530667,0,12.5678547,0.375724296,0.063083565,0.72795024,2.28014316,2.32117848,2.68080228,2984.6855
3699530727,0,11.07100962,0.248270022,0,1.075646718,3.69197658,2.89518588,5.54252868,4307.6929
3699530787,0,8.5762161,0.189157788,0,1.133894106,4.91839362,2.7699426,5.01656256,5584.7378
3699530847,0,8.71318638,0.393424056,0,1.298433456,4.90769874,3.43894356,6.23580426,5522.6235
3699530907,0,11.45070558,0.331532388,0,0.899581518,4.15253844,3.24028746,5.38362216,4534.5312
3699530967,4.0564125,13.3764021,0.38506554,0,0.311134716,0.425333916,0.2806434,2.65601826,487.12155
3699531028,4.82694156,12.51599742,0.17563012,0.08505671,0.283659804,0.032452614,0.206806986,1.679285034,213.13474
3699531088,5.38814718,10.9263033,0.153723218,0,0.28704159,0.055679416,0.21449448,1.614247056,171.78001
3699531148,2.77432182,10.05430734,0.101184973,0.077086654,0.300826782,0,0.158669199,1.198414206,161.81819
3699531208,5.4217602,9.10015326,0.004700275,0.124305583,0.244589832,0.090742865,0.11748506,0.028940845,146.62744
3699531268,0,9.99252036,0.296323182,0,0.790793586,1.356238386,1.06529274,2.25500742,1808.76
3699531328,0,7.9539453,0.203683176,0,1.335029202,3.83170806,3.54795138,5.10119424,4948.0879
3699531388,0,8.5116483,0.326274048,0.012663614,1.220064678,3.88665828,2.86699392,5.40053172,5235.4517
3699531448,0,7.69026492,0.388154862,0,1.133541756,4.38873552,3.63472272,4.61407716,5354.4355
3699531508,0,5.66861058,0.337877388,0,1.31410422,4.36109256,3.64146354,3.95080542,5433.8462
3699531568,0,9.42388938,0.536479614,0,1.071013032,4.87169406,3.31827714,4.23132156,5474.6416
3699531628,0,7.2269037,0.510959682,0,1.192545756,4.10580846,3.58726194,4.77725166,5487.5483
3699531689,0,10.3940577,0.153739942,0,1.355793138,4.38007176,3.38323554,3.8151333,5482.2817
3699531749,0,12.00197376,0.241834266,0,1.120729176,3.83487696,4.13882838,5.08351734,5494.7041
3699531809,0,10.05699726,0.424075698,0,1.016256276,4.57469982,3.68555994,3.97467198,5537.8555
3699531869,0,7.49239344,0.502025796,0,1.09017387,4.02729858,3.76563312,5.51562084,5537.4985
3699531929,0,12.7000296,0.418245408,0,1.251803358,3.7816731,4.17297996,5.46166026,5547.9302
3699531989,0,11.65515354,0.305957736,0,1.303744338,4.09062888,3.8410803,5.11376274,5565.5151
3699532049,0,7.26428808,0.503197596,0,1.088850258,3.80386764,3.50973216,4.8147858,5606.7046
3699532109,0,10.83804444,0.283823586,0,1.275316254,3.74544774,3.85409196,5.93865882,5605.4072
3699532169,0,8.67998718,0.443496744,0,1.051280136,4.17691134,3.95552952,4.81011012,5615.7993
3699532229,0,11.6790633,0.277210296,0,1.209688398,4.4138367,3.52347426,4.50780678,5616.252
3699532289,0,10.70566776,0.2872494,0,1.203769188,4.05086472,3.5514927,4.5111825,5618.9233
3699532350,0,11.05574292,0.408485646,0,1.507082382,3.60802692,4.68360594,4.17791736,5654.6753
3699532410,0,14.05578978,3.88573974,0,1.8994329,4.98170448,3.8067237,5.07598866,5601.5664
3699532470,0,18.4692816,18.0594576,0,1.785283794,8.97187842,4.321449,4.96454994,5608.4927
3699532530,11.01132036,21.6314838,30.8736702,0,1.371010392,10.9376775,3.7537164,6.96773106,5556.1851
3699532590,48.2080212,25.8355584,44.338365,0.203285124,1.791002268,14.39741394,4.438647,8.23187106,5526.957
3699532650,86.932809,24.4941048,60.9508638,-0.000310358,1.484490996,19.5413742,4.03592454,6.2337177,5492.4517
3699532710,145.6019856,25.939872,80.1207918,-0.000310358,2.10603384,22.9004496,3.82945806,7.44251202,5477.5449
3699532770,193.732038,31.2087798,89.733348,-0.000310358,3.28495158,26.850654,3.03449994,5.7880152,5452.7847
3699532830,233.235216,29.126061,102.2103144,-0.000310358,5.68138086,31.504941,4.49417556,6.74821944,5403.8755
3699532890,319.65669,21.6945324,119.6157204,1.60597071,2.30210982,35.0051742,3.8353833,7.80624882,5382.7188
3699532950,341.63235,24.2872326,134.984124,-0.00276268,3.94621704,39.1326768,3.08330784,7.36537176,5371.9614
3699533011,411.045336,26.012043,147.8959434,1.563118236,3.18136248,41.8527162,3.26985138,8.5235796,5367.0835
3699533071,412.33941,29.6834994,163.4993874,0.509642838,3.7329912,42.660684,3.33044442,8.80508106,5351.8369
3699533131,488.94939,20.328156,174.8000466,-0.005939266,4.21706124,46.7915238,4.22195364,9.20538846,5318.7358
3699533191,537.676164,25.7640498,190.602882,-0.005939266,2.84021766,56.0847384,3.67223076,8.85251538,5295.3403
3699533251,561.001248,28.4796882,200.634048,1.014080886,5.26591872,57.0802302,3.98711268,8.758548,5291.4341
3699533311,636.49089,27.41553,212.622336,1.088737182,7.2146934,59.4660078,4.3965315,8.89855416,5254.4014
3699533371,683.771976,26.3498346,225.03888,0.039347258,4.79632572,62.696043,3.58533306,10.05451848,5218.5801
3699533431,674.86635,34.9550658,230.7798,1.138685814,5.54027994,66.152637,3.2975064,8.01161586,5211.5859
3699533491,762.366078,22.9888368,244.581048,2.31551514,6.39670284,69.5673378,3.105342,11.268972,5172.3364
3699533553,787.88502,23.8950558,257.070078,-0.014548698,5.36058612,71.542557,3.8570904,11.9986092,5162.1372
3699533613,828.706194,30.9435876,266.55093,4.43563722,3.8698749,75.5033202,4.13334036,10.61030124,5168.5537
3699533673,858.006306,30.2359338,278.32896,1.396539,5.93190342,78.9848604,3.4744185,12.58004952,5147.3535
3699533733,928.194984,26.3226078,291.392136,4.30250274,1.9468179,79.470072,3.77957754,12.22443414,5182.7178
3699533794,947.294712,32.4446076,305.871714,-0.030112078,7.41376908,86.318784,3.84326136,12.72121362,5193.1982
3699533854,991.391094,34.5451284,311.429628,5.10698178,8.7474663,86.7157542,4.15150902,14.75405838,5146.9873
3699533914,1017.88659,27.9225864,326.56833,1.592438004,3.92357358,87.8886882,3.74656698,13.7072493,5145.0059
3699533974,1048.294008,33.09147,336.268926,0.159892286,5.63915556,93.6595386,3.58733124,13.83767514,5110.3052
3699534034,1102.627008,34.6279824,341.212032,3.9620502,7.07994648,96.4852164,4.52915892,14.8157811,5105.3564
3699534094,1121.974812,37.2884598,358.001046,0.953209548,3.4739289,97.4287764,3.17555802,16.36016184,5051.2993
3699534154,1181.016216,30.1558806,365.0823,3.02943204,3.78614196,97.0177158,5.20904124,15.81534126,5047.2964
3699534214,1228.035942,28.4015844,364.377852,3.19572324,8.74007208,103.929606,4.14730278,15.97904946,5008.2163
3699534274,1229.842314,33.798501,377.227656,1.446330348,4.48074468,104.8224312,4.44569742,17.21444832,5032.4473
3699534334,1254.2436,39.3076188,392.335074,2.01848886,5.11229898,105.3504198,3.61358964,16.9764741,4987.729
3699534394,1299.544182,27.8380098,396.213138,4.49291214,7.2543033,108.8361972,2.97513072,16.8807267,4967.6738
3699534455,1314.806184,26.7188562,410.510358,2.7450297,3.80054214,110.4448014,3.39278238,17.64151614,4956.2891
3699534515,1356.232536,32.7322926,417.461022,3.94445052,5.06552166,116.0558478,3.36575952,16.46449758,4961.5806
3699534575,1370.062026,33.5087856,425.595546,3.27065598,4.8558159,117.5656176,3.8280006,19.7645814,4962.4458
3699534635,1408.45122,39.8131074,423.065808,5.51437326,8.27400888,121.8148686,3.90698586,19.8759582,4936.9849
3699534695,1468.77714,34.67025,434.509686,6.13363392,7.06894092,120.9071502,3.49554006,19.2735216,4925.4536
3699534755,1456.685604,36.5530212,435.287376,5.31032202,5.8780512,120.3976728,2.2991634,18.7072686,4903.4097
3699534815,1511.965944,36.8994582,446.929128,6.32021364,9.3981609,120.6163962,3.3567075,20.5496208,4872.6597
3699534875,1547.58186,32.8440672,459.56259,6.91815006,7.5137121,123.2513442,3.59045784,18.5425326,4888.9565
3699534935,1580.817816,38.7752292,466.15446,9.00236628,9.79142076,128.3413644,3.83292342,19.7490906,4882.5283
3699534995,1569.478266,35.485497,467.711892,3.42674262,11.14281972,131.2743438,3.73632318,20.7715968,4854.8696
3699535055,1608.648264,40.0210236,471.051396,6.75940194,8.7549156,131.3520174,2.08802898,22.423995,4833.083
3699535115,1626.61707,34.382709,469.40877,5.3113374,11.10452814,130.6751634,3.07786824,23.1730362,4812.4312
3699535176,1650.417732,41.222646,480.932064,5.20194654,6.68303442,137.93589,3.53321856,23.4456444,4809.4561
3699535236,1654.13034,36.6733494,485.68491,2.00156778,15.83899092,136.0539468,3.66697458,21.2349024,4801.5806
3699535296,1667.879298,45.3392784,499.458528,7.78789044,7.0832556,140.003325,2.81586546,25.391547,4804.9775
3699535356,1721.331072,49.3371216,503.898588,13.7732832,5.75734572,140.5015002,3.09565206,24.7174092,4802.3911
3699535416,1728.202374,46.0726434,499.100202,7.33307022,11.62499076,137.6690868,2.90109006,23.014035,4771.1577
3699535476,1758.615606,45.3189852,514.852398,5.18834718,11.55912516,138.8074356,3.61188018,23.8269384,4735.7041
3699535536,1777.62591,41.7542274,511.476192,6.42934692,12.90501054,141.762249,4.0629771,23.1848604,4741.7778
3699535596,1800.43596,42.3287874,518.471514,10.09199556,9.84045402,142.3274274,1.94254146,23.5169712,4722.9409
3699535656,1816.66062,42.0190002,525.404394,9.46986804,8.07529878,143.272746,2.52416502,25.0460658,4704.6816
3699535716,1861.21098,44.9434728,524.687148,11.08588482,8.95587786,150.9080526,3.14848818,26.5646052,4699.1543
3699535776,1888.47378,43.0974738,535.299498,8.69371326,9.60019686,148.1500584,2.3560974,26.235414,4675.335
3699535837,1874.89926,38.7939096,543.303198,5.91939198,9.2574225,152.9403984,2.56657464,24.776019,4659.9219
3699535897,1910.9889,37.1468826,542.5992,11.10709872,7.9912071,159.2036082,2.1323916,24.8749092,4621.1743
3699535957,1897.85574,42.3538362,542.920608,7.09919964,12.6046863,152.1125244,2.35600992,25.7099814,4621.0498
3699536017,1931.16906,45.2423556,542.71917,15.37627266,5.2879617,156.212622,3.12165198,28.654146,4609.4146
3699536077,1921.4001,41.1519564,553.142124,8.20552626,8.03439792,153.2374974,3.1207266,25.6790322,4608.7661
3699536137,1919.01114,47.2759938,555.473034,8.79707052,11.14721424,157.1493996,3.22561926,28.3075776,4595.0713
3699536197,1983.03588,57.3283188,561.007782,13.4583489,8.62010226,157.8001464,2.94078978,26.4542022,4598.644
3699536257,1996.488,47.3578614,564.404256,14.68398636,11.13936336,159.922773,2.79899604,28.4450706,4612.0649
3699536317,2012.16078,48.9935034,571.685238,13.46379228,5.54733738,160.4410956,3.61707174,28.7233056,4611.0859
3699536377,2045.51244,48.7964664,566.079066,18.5625324,8.21254896,166.4104194,4.03852914,30.2172012,4547.0215
3699536437,2013.80958,52.641513,574.793874,6.70928328,15.59132658,160.8712776,2.83497048,27.5545188,4567.9419
3699536498,2047.2066,51.7209624,569.83986,12.11154102,10.63966824,163.1290374,3.05319672,28.7730288,4544.2622
3699536558,2064.2796,55.760868,584.578836,8.26609446,12.0874302,168.419889,4.32440244,30.6165078,4525.5552
3699536618,2060.02134,49.9032702,574.336836,9.35727192,14.57076186,163.1311794,4.24699596,29.2909284,4505.3008
3699536678,2067.53058,51.6858948,575.76483,10.40914332,7.30994652,166.9953456,3.72397554,30.364902,4496.709
3699536738,2091.94146,53.5785336,586.47348,15.27893892,5.32944666,169.0276788,1.336843548,30.0706848,4468.8213
3699536798,2053.29636,51.9782202,577.98495,11.61070344,15.57591822,166.4414982,3.66550722,29.944467,4482.8633
3699536858,2078.70948,52.6518576,587.722626,15.06148848,10.16117586,165.1798008,2.71331586,30.3969654,4468.666
3699536918,2122.41564,48.9494952,591.496002,10.30134168,15.99520806,167.7514248,3.91001796,31.4242974,4449.0532
3699536978,2129.30604,48.249783,586.029528,14.7360717,12.32911062,172.6378974,2.84910912,32.4357426,4446.77
3699537038,2128.59828,56.8112202,592.591662,10.70713638,9.6505992,169.4387196,3.27166236,30.9429756,4452.6045
3699537098,2131.47774,55.0437876,595.696734,13.31308656,11.7000198,166.0944942,1.8352872,29.6064918,4455.7876
3699537161,2182.3479,51.978753,606.216582,12.93999084,10.55662704,170.4511368,2.61873594,32.2044642,4459.4863
3699537221,2190.16926,54.0085896,598.37454,13.74780942,12.6880056,173.8822086,3.4692975,33.4356948,4440.6675
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