---
instrument_id: '482'
data_file_original_name: '190725_CIMS_pos.csv'
skip_headers: '1'
charts: ''
headers:
    - '?Time_since_pinene_injection (h)'
    - 'm/z 136 (norm. counts)'
    - 'm/z 137 (norm. counts)'
    - 'm/z 138 (norm. counts)'
    - 'm/z 139 (norm. counts)'
    - 'm/z 140 (norm. counts)'
    - 'm/z 141 (norm. counts)'
    - 'm/z 142 (norm. counts)'
    - 'm/z 143 (norm. counts)'
    - 'm/z 144 (norm. counts)'
    - 'm/z 145 (norm. counts)'
    - 'm/z 146 (norm. counts)'
    - 'm/z 147 (norm. counts)'
    - 'm/z 148 (norm. counts)'
    - 'm/z 149 (norm. counts)'
    - 'm/z 150 (norm. counts)'
    - 'm/z 151 (norm. counts)'
    - 'm/z 152 (norm. counts)'
    - 'm/z 153 (norm. counts)'
    - 'm/z 154 (norm. counts)'
    - 'm/z 155 (norm. counts)'
    - 'm/z 156 (norm. counts)'
    - 'm/z 157 (norm. counts)'
    - 'm/z 158 (norm. counts)'
    - 'm/z 159 (norm. counts)'
    - 'm/z 160 (norm. counts)'
    - 'm/z 161 (norm. counts)'
    - 'm/z 162 (norm. counts)'
    - 'm/z 163 (norm. counts)'
    - 'm/z 164 (norm. counts)'
    - 'm/z 165 (norm. counts)'
    - 'm/z 166 (norm. counts)'
    - 'm/z 167 (norm. counts)'
    - 'm/z 168 (norm. counts)'
    - 'm/z 169 (norm. counts)'
    - 'm/z 170 (norm. counts)'
    - 'm/z 171 (norm. counts)'
    - 'm/z 172 (norm. counts)'
    - 'm/z 173 (norm. counts)'
    - 'm/z 174 (norm. counts)'
    - 'm/z 175 (norm. counts)'
    - 'm/z 176 (norm. counts)'
    - 'm/z 177 (norm. counts)'
    - 'm/z 178 (norm. counts)'
    - 'm/z 179 (norm. counts)'
    - 'm/z 180 (norm. counts)'
    - 'm/z 181 (norm. counts)'
    - 'm/z 182 (norm. counts)'
    - 'm/z 183 (norm. counts)'
    - 'm/z 184 (norm. counts)'
    - 'm/z 185 (norm. counts)'
    - 'm/z 186 (norm. counts)'
    - 'm/z 187 (norm. counts)'
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    - 'm/z 247 (norm. counts)'
    - 'm/z 248 (norm. counts)'
    - 'm/z 249 (norm. counts)'
    - 'm/z 250 (norm. counts)'
dataset_id: '2203'
experiment_link: 'https://icarus.ucdavis.edu/chambers/552/experiments/565'
experiment_set_link: 'https://icarus.ucdavis.edu/chambers/552/experimentSets/214'
chamber_link: 'https://icarus.ucdavis.edu/chambers/552'
dataset_created_at: '2021-08-12 14:45:55'
dataset_updated_at: '2021-08-12 14:45:55'
instrument_link: 'https://icarus.ucdavis.edu/chambers/552/instruments/482'
instrument:
    id: '482'
    short_name: 'CF3O- CIMS: positive mode, raw spectra'
    full_name: 'chemical ionization mass spectrometer'
    manufacturer: 'Varian'
    model: '1200'
    year: ''
    data_recording_software: 'Varian workstation'
    data_analysis_software: 'Matlab'
    raw_data_time_resolution: '0.125 s'
    analysis_data_averaging: '0.5 s averages of raw data'
    detection_limit: '100 ppt'
    quantification_limit: ''
    sensitivity_to_temperature: 'uncertain'
    sensitivity_to_relative_humidity: 'Compound-dependent'
    sampling_method: 'Direct sampling'
    sample_preparation_method: ''
    sample_residence_time_in_seconds: ''
    length_of_tubing_in_cm: '100'
    flow_rate: '2 lpm'
    tubing_material: 'FEP Teflon'
    chemical_identification_method: 'This CIMS is predominantly for use in negative mode, but can also be operated in positive mode, such that species can be observed typically as [M+H], unless an additional co-reagent is added. We do not calibrate in positive mode, so only normalized counts are reported.'
    data_analysis_method: ''
    quantification_method: 'Baseline correction, dilution correction'
    calibration_method: 'N/A'
    calibration_drift_estimate: 'Low (on the order of weeks)'
    calibration_schedule: 'As Needed'
    uncertainty_estimation_method: 'Uncertainties are estimated from propagating uncertainties in the steps of the absolute calibrations'
    known_interferences: ''
    link_to_supplemental_information: 'St. Clair et al. (DOI 10.1063/1.3480552)'
    additional_notes: ''
    organization_id: '559'
    created_at: '2021-08-11T00:36:31.000000Z'
    updated_at: '2021-08-11T00:36:50.000000Z'
    column_descriptors: ''
    sampling_protocol: 'Online'
    skip_headers: '1'
    tubing_inner_diameter: '0.16 in'
    what_is_measured: 'VOCs (esp. carbonyls)'
    measurement_uncertainty: '+/- 50% unless otherwise noted'
    measurement_units: 'normalized counts'

---
?Time_since_pinene_injection (h),m/z 136 (norm. counts),m/z 137 (norm. counts),m/z 138 (norm. counts),m/z 139 (norm. counts),m/z 140 (norm. counts),m/z 141 (norm. counts),m/z 142 (norm. counts),m/z 143 (norm. counts),m/z 144 (norm. counts),m/z 145 (norm. counts),m/z 146 (norm. counts),m/z 147 (norm. counts),m/z 148 (norm. counts),m/z 149 (norm. counts),m/z 150 (norm. counts),m/z 151 (norm. counts),m/z 152 (norm. counts),m/z 153 (norm. counts),m/z 154 (norm. counts),m/z 155 (norm. counts),m/z 156 (norm. counts),m/z 157 (norm. counts),m/z 158 (norm. counts),m/z 159 (norm. counts),m/z 160 (norm. counts),m/z 161 (norm. counts),m/z 162 (norm. counts),m/z 163 (norm. counts),m/z 164 (norm. counts),m/z 165 (norm. counts),m/z 166 (norm. counts),m/z 167 (norm. counts),m/z 168 (norm. counts),m/z 169 (norm. counts),m/z 170 (norm. counts),m/z 171 (norm. counts),m/z 172 (norm. counts),m/z 173 (norm. counts),m/z 174 (norm. counts),m/z 175 (norm. counts),m/z 176 (norm. counts),m/z 177 (norm. counts),m/z 178 (norm. counts),m/z 179 (norm. counts),m/z 180 (norm. counts),m/z 181 (norm. counts),m/z 182 (norm. counts),m/z 183 (norm. counts),m/z 184 (norm. counts),m/z 185 (norm. counts),m/z 186 (norm. counts),m/z 187 (norm. counts),,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,m/z 247 (norm. counts),m/z 248 (norm. counts),m/z 249 (norm. counts),m/z 250 (norm. counts)
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-0.321136426,0.011620285,0.014382775,0.0145565,0.0244925,0.00720675,0.0159115,0.0052047,0.000485725,0.0084805,0.00428925,0.01133525,-0.00805,0.00439925,-0.0687125,-0.018016,0.004364,0.01347925,0.0185325,0.0104007,0.00817175,0.001092495,0.033133,0.008812013,0.06311375,0.016759,0.00172,0.01471065,0.0037745,0.015781175,0.01819,0.008627375,-0.00234,0.006129375,0.0103875,0.00221675,0.0323415,0.00856875,0.006354625,0.006747,0.01922825,0.016058975,0.0155935,0.003971,-0.0224875,0.0020866,0.0084655,0.00947984,0.01150505,0.00789175,0.03700175,0.01407825,0.015010625,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
-0.269173446,0.003205575,-0.001075325,0.0040675,0.0014595,-0.00697625,-0.0006485,-0.0027535,-0.008336015,0.0014755,-0.00377375,-0.00036575,-0.020854,-0.01203675,-0.0401525,-0.002735,0.000813,-0.00131875,0.0082065,-0.0010365,0.00468075,-0.003415785,0.014061,-0.004546328,0.02653375,0.0020056,-0.00456,-0.00632675,0.0097295,-0.000754525,-0.00176,-0.004860025,-0.007137,0.002529475,0.0082975,-0.00272825,0.0067825,-0.00392625,-0.001702375,-0.000948,0.00539325,0.004601575,0.0031285,-0.004652,-0.0163475,-0.0014736,-0.0067195,-0.00846055,0.00575085,-0.00222625,0.01976675,-0.00286875,-0.004195075,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
-0.217224044,0.001195475,0.004454175,0.0050695,0.0098185,0.00675375,0.0121475,-0.0010605,0.003031025,0.0061665,0.00285825,0.00571525,-0.0019,0.00067525,-0.0255625,-0.007395,-0.004587,-0.00167075,-0.0058105,0.0012365,-0.00894925,-0.003415785,0.012503,-0.003752138,0.01378375,-0.0026704,0.00105,0.00114825,-0.0066015,-0.004630525,0.002568,0.005484075,0.004468,-0.000662325,0.0001875,-0.00407325,-0.0027485,0.00570375,-0.003772175,-0.001613,0.01148925,-0.003801525,0.0046475,0.001885,-0.0148575,-0.000883,0.0022005,0.00351725,0.00058875,-0.00243925,-0.00165625,0.00171325,0.000629625,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
-0.165603152,-0.002626525,-0.001110125,-0.0004995,-0.0012055,-0.00440525,-0.0034035,-0.0031655,-0.004687675,0.0010195,-0.00292475,-0.00570175,-0.01693,-0.00463075,-0.0064225,-0.008125,-0.0063,-0.00271875,0.0001355,-0.0013345,0.00708875,0.003220695,0.002992,-0.002843788,-0.00864425,0.0054802,0.00545,-0.00061875,0.0030585,-0.003007525,-0.003091,-0.003058025,-0.005792,-0.000989325,-0.0057725,0.00091975,9.65E-05,-0.00345425,0.006304625,0.000795,-0.00782975,-0.006263525,0.0067925,-0.00217,0.0070725,-0.0014339,0.0038985,-0.00137655,0.00261875,-0.00514925,0.00718375,1.52E-05,-0.002557075,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
-0.113937618,-0.006175525,-0.006014425,-0.0076325,-0.0047845,-0.00852425,-0.0029715,0.0029105,-0.001173375,-0.0069075,-0.00067075,-0.00188475,0.00526,-0.00364275,0.0247375,0.003705,0.002064,-0.00010775,-0.0021575,-0.0046755,0.00232875,-0.004140505,-0.007034,-0.002943088,0.00358075,-0.0040844,-0.0156,-0.00307575,-0.0064875,0.002561675,-0.003135,0.000519975,-0.004194,-0.003149325,-0.0031325,-0.00443125,0.0043005,-0.00782725,-0.006795075,-0.00197,-0.00716475,0.003484775,-0.0064165,-0.005773,0.0141825,-0.0062338,-0.0034385,-0.00586455,-0.00575525,-0.00103425,-0.00778625,-0.00761875,-0.002090475,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
-0.061921165,0.007606575,0.002670375,0.0030625,-0.0038285,0.00617575,-0.0057725,0.0013155,0.002830025,-0.0002785,0.00073725,0.00187125,0.01357,0.00759825,0.0072475,0.011815,0.008823,0.00449725,0.0078325,0.0047735,-0.00046825,0.004335595,-0.008461,0.009539013,-0.00872025,0.0012746,0.0091,0.00254625,0.0100305,0.005076375,0.003658,-0.002946025,0.005518,0.004800975,0.0087175,0.00758475,-0.0016485,0.00557775,0.004262625,0.002788,0.00350525,0.006580275,-0.0050235,0.006058,-0.0063975,0.0085507,-0.0026605,0.00372385,0.00254775,0.00862275,0.00225875,0.00589025,0.004017925,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
-0.009975684,0.010956975,0.007827655,0.0097835,0.0115685,0.00423975,-0.0021795,0.0021485,-0.001512775,0.0022635,-0.00439575,0.00727125,-0.00417,0.00937485,0.0463275,0.006595,0.019981,-0.00534575,0.0139825,0.0043665,0.00693275,2.21E-04,0.008078,0.001909613,-0.01074125,-0.0063304,0.01362,0.00351425,0.0153065,0.010859045,0.007386,0.001198975,-0.005878,0.003852875,0.0134775,0.00966875,-0.0039465,0.00072275,0.004410625,0.011375,-0.00328475,0.003740975,0.0095455,-0.002326,0.0097225,0.0062579,0.0239695,0.00742175,0.00152475,0.00590275,-0.00479025,-0.00139575,0.012664625,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
0.041679145,0.500649475,0.864563575,0.1097895,0.0328615,0.00942975,0.0312645,0.0218777,0.013828025,0.0177629,0.02268425,0.00650025,0.00773,0.00495025,0.0443675,0.034175,1.517067,0.50324925,0.7562385,0.0902615,0.28198175,0.042151795,0.041437,0.008787013,-0.00349625,0.0079633,0.01898,0.00519525,0.0149675,0.011924375,0.02454848,0.386582975,0.177437,0.228648675,15.3294375,1.89566975,0.4319775,0.05582275,0.084994625,0.024542,0.00268925,0.009065175,0.0177035,0.008876,0.0387225,0.0182587,0.0197135,0.03843845,0.11565775,0.05646575,0.12238975,0.07758425,0.076560625,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
0.093877756,0.392359475,0.656143575,0.0761285,0.0306695,0.00905975,0.0495475,0.0141561,0.018124025,0.0124235,0.00442525,0.01560525,0.02436,0.00204325,0.0856675,0.037295,2.054267,0.77218925,0.9952585,0.1185715,0.22390175,0.032519795,0.050974,0.006288013,-0.00815025,-0.0046024,0.01459,0.00875115,0.0092365,0.007389475,0.0217062,0.274742975,0.202247,0.308158675,20.2304375,2.40876975,0.5919075,0.05755175,0.081665625,0.012259,-0.00178075,0.006272475,0.0138285,0.004172,0.0377825,0.0150337,0.0135355,0.04011245,0.18207775,0.04556775,0.16534975,0.09369325,0.098630625,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
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0.197262238,0.314279475,0.402353575,0.0539055,0.0402685,0.01363625,0.0888585,0.0284465,0.017235025,0.0068495,0.00261325,0.00257625,0.03383,-0.00063175,0.0690975,0.051265,2.312067,0.93193925,1.2454585,0.1204285,0.21428175,0.030275795,0.04127,0.005165713,-0.00412925,0.0077319,0.01798,0.01703545,0.0146065,0.007032075,0.038439,0.185622975,0.237237,0.393888675,23.0304375,2.83706975,0.6247675,0.06731075,0.066203625,0.012676,0.00261225,0.013524435,0.0142955,0.001635,0.0246525,0.0244647,0.0263465,0.04020145,0.28886775,0.07434175,0.26283975,0.11392525,0.128935625,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
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0.300230465,0.259689475,0.234913575,0.0321585,0.0543095,0.01117275,0.0973585,0.0180861,0.023622025,0.0009415,0.00997325,0.00061425,0.01509,-0.00564175,0.1130675,0.056385,2.353967,1.07163925,1.3283585,0.1526985,0.19002175,0.024451795,0.065368,0.004534113,0.00986375,-0.0067234,-0.00694,0.01178765,0.0071845,0.000344475,0.0269466,0.092617975,0.264397,0.464748675,24.9484375,2.94716975,0.6803775,0.06847575,0.050636625,0.006445,-0.00502775,0.006271275,0.0157435,-0.007226,0.0443725,0.0159057,0.0003355,0.04373945,0.34002775,0.07940875,0.33024975,0.11197825,0.130625625,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
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0.662745972,0.151159475,0.028387575,0.0196665,0.0618905,0.02499315,0.1309785,0.0308835,0.039184025,0.0141859,0.00118825,0.01383325,0.03194,0.00692725,0.1673475,0.081735,2.557467,1.22273925,1.4873585,0.1940685,0.22810175,0.038723795,0.082275,0.017625013,0.01263375,0.0065803,0.02956,0.02476925,0.0270025,0.013901775,0.047433,0.016754775,0.301407,0.526558675,28.3294375,3.42896975,0.8137075,0.08486775,0.034669625,0.0167708,0.01821825,0.024945475,0.0285015,0.006386,0.0696725,0.0298157,0.0205795,0.04653545,0.41075775,0.11680175,0.46350975,0.15676625,0.187615625,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
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