---
instrument_id: '415'
data_file_original_name: '130410_CIMS.csv'
skip_headers: '1'
charts: ''
headers:
    - 'exp_time(min)'
    - 'formic_acid(ppb)'
    - 'acetic_acid(ppb)'
    - 'PAA(ppb)'
    - 'mz145(ppb)'
    - 'hydroxyacetone(ppb)'
    - 'IEPOX(ppb)'
    - 'H2O2(ppb)'
dataset_id: '3510'
experiment_link: 'https://icarus.ucdavis.edu/chambers/553/experiments/623'
experiment_set_link: 'https://icarus.ucdavis.edu/chambers/553/experimentSets/215'
chamber_link: 'https://icarus.ucdavis.edu/chambers/553'
dataset_created_at: '2021-09-01 15:30:53'
dataset_updated_at: '2021-09-01 15:30:53'
instrument_link: 'https://icarus.ucdavis.edu/chambers/553/instruments/415'
instrument:
    id: '415'
    short_name: 'CIMS'
    full_name: 'Chemical Ionization Mass Spectrometer with CF3O-'
    manufacturer: 'Varian'
    model: '1200 triple quadrupole mass analyzer'
    year: ''
    data_recording_software: ''
    data_analysis_software: 'matlab'
    raw_data_time_resolution: '162 to 172 s'
    analysis_data_averaging: 'signal for the compound is normalized to the 86 signal'
    detection_limit: 'ppb'
    quantification_limit: ''
    sensitivity_to_temperature: ''
    sensitivity_to_relative_humidity: 'Must account for the water signals'
    sampling_method: ''
    sample_preparation_method: ''
    sample_residence_time_in_seconds: ''
    length_of_tubing_in_cm: ''
    flow_rate: ''
    tubing_material: ''
    chemical_identification_method: 'In this analysis, benzyl alcohol concentration comes from the 193 scan'
    data_analysis_method: 'To get the concentration of benzyl alcohol in ppb, one takes the 193 signal at a given time and divides by the 86 signal (interpolated to that exact time) and then uses that signal to compare to the calibrated ppb/normalized signal value'
    quantification_method: ''
    calibration_method: 'The 193 m/z signal (the mass of benzyl alcohol + CF3O-), which was measured every 162 to 172 s, was normalized to the 86 m/z signal (the M+1 peak for CF3O-) and used to measure the benzyl alcohol concentration. This signal was calibrated using dilutions of a 800 L Teflon bag of ~44 ppb benzyl alcohol. The concentration in this bag was verified using fourier transform infrared absorption (FT-IR) spectroscopy with a 19 cm pathlength and absorption cross sections from the Pacific Northwest National Laboratory (PNNL) database. In this way, any wall or sampling loss was accounted for since the CIMS sampled from the same volume as the FT-IR. Multiple FT-IR samples were taken until they gave the same concentration; this was to ensure a minimal effect from any compound deposited on the instrument walls.'
    calibration_drift_estimate: ''
    calibration_schedule: ''
    uncertainty_estimation_method: 'During the background collection period of ~1 h for each experiment, the standard deviation of the benzyl alcohol mixing ratio along with the uncertainty in the calibration was used to estimate the uncertainty of the initial benzyl alcohol mixing ratio. This combined standard deviation was also used as the uncertainty in the measurement of the time-resolved gas-phase mixing ratios throughout the experiment. Since the number that matters for the SOA yield is the reacted benzyl alcohol, which is the measured benzyl alcohol subtracted from the initial benzyl alcohol, the variance of the reacted benzyl alcohol is the sum of the variances of the initial and measured benzyl alcohol mixing ratios. The uncertainty reported is, then, the square root of the reacted benzyl alcohol mixing ratio variance.'
    known_interferences: ''
    link_to_supplemental_information: ''
    additional_notes: ''
    organization_id: '540'
    created_at: '2020-03-12T23:50:47.000000Z'
    updated_at: '2020-03-12T23:50:47.000000Z'
    column_descriptors: "Local time (reported at the time of signal 50, the rest of the signals are taken in the order they appear)\r\nBenzyl alcohol mixing ratio in ppb (found from the normalized signal, nan if it's not during the background or experiment period)\r\nUncertainty in the benzyl alcohol mixing ratio in ppb (found from the background and the calibrations)\r\nm/z signals for each m/z measured (these are not normalized)"
    sampling_protocol: 'Online'
    skip_headers: '1'
    tubing_inner_diameter: ''
    what_is_measured: 'Gas-Phase Compounds'
    measurement_uncertainty: 'For benzyl alcohol, this is given in the third column'
    measurement_units: 'ppb (otherwise, just signal)'

---
exp_time(min),formic_acid(ppb),acetic_acid(ppb),PAA(ppb),mz145(ppb),hydroxyacetone(ppb),IEPOX(ppb),H2O2(ppb)
0,0.44743779,0.01443924,0.043846947,-0.34159112,0.022159207,-0.006996797,716.3069291
3.79872797,-0.727434324,0.220486131,0.052557013,-0.157939078,-0.011403185,-0.212823236,707.1013796
7.618467409,-0.462884194,0.528593762,-0.076548477,0.012750316,-0.016849367,-0.175273123,722.2359955
11.45575743,-0.094591746,0.026210912,-0.035856029,-0.314995714,-0.047187493,-0.248258354,723.4135633
15.26704191,-0.773439805,-0.174683676,-0.233991273,-0.369280329,-0.067614283,-0.136089913,715.7167778
19.10079563,-0.606465221,-0.38331205,0.074165818,-0.146879805,0.108391044,0.207665956,716.0667817
22.887175,0.099327156,-0.375270049,-0.095291358,-0.124560344,0.054538437,0.455747758,708.3067602
26.67450512,-0.506720014,-0.178806905,-0.030625042,-0.042415549,0.1066788,1.092984895,709.3564838
30.45837021,0.102628431,-0.052388429,-0.146722028,-0.039359955,0.21940064,1.718385561,719.4115295
34.27349109,-0.012887694,-0.188285659,0.017466166,-0.165628859,0.070523126,2.810032454,721.1951927
38.0675745,0.113290866,-0.369780103,-0.087841144,0.237609652,0.050112051,3.226725545,715.7168098
41.85079571,0.195817024,-0.256122753,-0.067570152,-0.295944205,-0.0196019,3.583700883,717.532037
45.67739629,-0.485020354,-0.427045225,-0.053047354,-0.246412192,-0.000221412,4.218490921,717.6002962
49.45494406,-0.171167861,0.15969804,0.01531299,-0.201084463,-0.116131634,4.500343032,716.4459605
53.23895248,-0.001950117,-0.007222458,-0.001765392,-0.125878761,0.101978269,5.199788287,713.762404
57.04471328,0.057270753,0.009808355,-0.079155911,-0.040057939,0.097992558,5.668940002,716.2065252
60.8327335,-0.417824712,-0.207824199,-0.016622122,0.081688882,0.246749037,6.407536586,722.4715505
64.64204926,-0.25095668,-0.092578416,-0.085779497,-0.138466335,0.006819781,5.927501836,721.0096685
68.44797054,-0.346924065,-0.32951536,-0.14146385,0.024059199,0.228262823,6.385846854,717.8553038
72.2621967,-0.025709761,-0.111207265,0.015758207,-0.076356376,0.035643774,6.921499028,722.8092771
76.05481683,-0.403862004,-0.413656566,-0.150064845,0.133891523,0.290070856,7.692947131,707.1889613
79.84100965,-0.219672272,-0.097597198,-0.07983245,-0.19749266,0.171944235,7.983271896,720.4905116
83.64580842,0.101976945,-0.211961604,0.012130625,-0.223227613,0.061837394,8.740610116,717.3048622
87.45959051,-0.451880627,-0.233260922,-0.190423755,0.077553953,-0.024008027,8.886715508,714.2059199
91.25782318,0.120550403,-0.382359894,0.07543935,0.098427974,0.167443464,9.999096517,718.9640358
95.06249851,-0.616854076,-0.205821111,-0.0516195,-0.354635002,-0.079881665,10.03168312,710.2702696
98.84618936,-0.612769065,-0.260156677,0.047229737,-0.014173153,0.268998493,10.86369387,712.8720179
102.668929,0.03782844,-0.095947985,-0.200627104,-0.08319056,0.11678413,11.66594551,715.5644975
106.4909167,-0.660573896,0.01336496,0.048268415,0.09000274,0.149371904,12.01822869,723.8910097
110.316351,0.313851391,-0.020195912,0.190064728,0.213771981,0.215358125,12.87248522,723.4255153
114.1252309,-0.960626676,-0.256801482,-0.046212426,-0.044176889,0.093072298,12.28469858,726.5449809
117.9292358,-0.715422374,-0.132914935,-0.216045904,0.066873343,0.075492174,12.11238989,705.0479666
121.749361,-0.776144619,-0.492165048,-0.077494197,0.013239393,0.271706876,12.40124862,723.6857069
125.5587963,-0.543373818,0.010228716,-0.081602745,-0.046762198,0.149671814,12.68035907,718.9897074
129.3552774,-1.003634797,-0.221729282,-0.18146754,-0.138131311,0.026928187,13.38464081,713.6493628
133.1460329,-0.807863398,0.008300083,0.043387362,0.004000498,0.187045951,13.76981023,727.100868
136.9533041,-0.43542136,-0.007811807,-0.130392941,0.250829413,0.176436257,14.49821713,722.7781409
140.7584687,-0.578281222,-0.364939042,-0.101263931,0.231392377,0.227727887,14.66934957,720.4922063
144.5622087,-0.225593649,0.300096915,0.019169012,0.032183251,0.397977246,15.34235148,715.1812034
148.3793059,-0.472755606,-0.120777508,0.006380245,-0.02764651,0.319460159,14.64782677,718.8704041
152.1956339,-0.219374129,0.143083719,-0.066004556,-0.20491246,0.250161188,15.26685103,717.0716793
155.9868969,-1.054233786,-0.032415299,0.003892841,0.288358292,0.169251552,15.14934454,719.9651417
159.8126192,-0.643147521,0.00850091,-0.008992674,-0.029507846,0.241068884,15.69877616,724.7192707
163.5882569,-0.062032063,-0.549003228,0.136714641,-0.081199299,0.230293477,15.38398013,723.3472801
167.3842334,-0.444057039,0.17391851,-0.094258845,-0.000405493,0.209426284,14.98815183,714.3094435
171.1961313,-1.022059475,-0.515587907,-0.175022025,-0.202834117,0.24868197,15.43331545,717.9313157
175.0067309,-0.429353713,-0.482983629,-0.040913996,-0.134491764,0.127258477,14.74133036,713.571117
178.795864,-1.128849459,0.050884187,-0.045983149,-0.05563068,0.31250974,14.97103065,716.6355189
182.5918653,-0.569843955,-0.324934239,0.031291667,0.180891547,0.254607898,14.90628369,709.447697
186.3917726,-0.380944457,-0.321452746,-0.129708112,0.042257358,0.240809691,15.51310817,709.5916568
190.2098154,-0.267387035,0.156665493,0.039009595,-0.165175975,0.246563291,15.73856637,732.2240425
194.0010045,-0.518535774,-0.322824331,0.097530867,0.338986915,0.187549155,15.6428106,725.1336891
197.7960284,-1.617729072,-0.128891891,0.097010835,0.141243852,0.231587126,15.41260073,712.254928
201.5960924,-1.001009925,-0.053093049,-0.140765484,-0.033765517,0.173183202,15.86146981,711.8021073
205.4085493,-0.504743978,-0.108293513,-0.054328599,-0.077709952,0.179552984,15.2420814,721.8806384
209.2038607,-1.260467994,-0.427445722,-0.136591765,-0.137475575,0.004151002,15.83901519,713.6469828
212.9972434,-1.580321897,0.00893357,-0.059483345,-0.208653933,0.229778216,15.74941562,710.5089227
216.8257201,-1.221715776,0.0422102,-0.018810907,0.33862245,0.340426579,15.53757935,717.5313648
220.6496232,-0.42366299,-0.42637871,-0.110394507,-0.103153993,0.28043022,15.61853722,715.7057087
224.4420121,-0.895770026,-0.017422173,0.056971308,0.026751264,0.364419719,15.80687543,726.7406051
228.2412429,-0.615336481,-0.032171549,-0.117930309,-0.120272579,0.418931699,15.56396614,713.8279857
232.0510942,-1.116855803,-0.235223353,0.166244024,0.158498992,0.274022514,16.2142676,722.5364637
235.8629439,-0.419429351,-0.085805455,-0.071600945,-0.369119865,0.124223619,15.74438655,709.3078547
239.6793317,-0.813834964,0.247691212,-0.064230651,-0.062768403,0.292147259,15.73197034,708.1097231
243.4793613,-0.44546434,-0.065858028,-0.00195774,0.265491534,0.294807919,15.50419171,733.6002793
247.2897821,-1.051810507,-0.388471671,-0.074796192,0.095888462,0.214758615,15.60052111,706.6374937
251.0718927,-0.825936588,0.01911386,0.017989257,0.09000396,0.274380507,15.95246334,724.1502604
254.8820942,-0.64713211,-0.058133252,0.06735534,-0.045061431,0.266923465,15.40001927,713.7652782
258.6960083,-0.490146009,-0.317703255,0.014915704,0.160665389,0.064337018,14.70903174,715.7900803
262.5027295,-0.647383039,-0.38368735,0.023556741,-0.101722011,0.163040501,14.88749785,721.9157594
266.3149175,-0.520123287,0.027637331,0.128332135,0.283595387,0.231734422,15.09605683,720.0045641
270.1174779,-0.131748348,-0.122486135,0.140150556,0.299422031,0.285460219,15.02974544,718.0723238
273.9300574,0,0,0,0,0,15.5566674,0
277.7458896,0,0,0,0,0,0,0
281.5386144,0,0,0,0,0,0,0
285.3687789,0,0,0,0,0,0,0
289.178946,0,0,0,0,0,0,0
292.988157,0,0,0,0,0,0,0
296.8041002,-0.577744428,-0.378289979,0.002218113,0.130534625,0.267585303,12.06778788,722.3678835
300.6240737,-0.451001783,-0.390211081,0.042593889,0.073071656,0.141094687,12.00604575,717.9414962
304.4246813,-0.179340488,-0.121589755,-0.076108634,0.174334101,0.159669791,12.38053886,714.9669751
308.2266795,-0.009740978,0.118630379,0.134169297,0.383897243,0.379751142,10.70730559,727.677505
312.0524755,-1.232308446,-0.180502226,0.027485545,0.23031578,0.434170242,6.332099736,727.2614869
315.8654894,-0.185757208,-0.163571918,0.05907621,0.40042022,0.03503264,4.50307921,721.7038033
319.6715601,-0.991253214,-0.416894559,-0.004300818,-0.024649977,-0.090411853,3.102772979,719.2175324
323.4751873,0.190330463,0.26203311,-0.047326297,0.176619318,0.144552924,2.195259991,712.0347868
327.2634374,-0.264653158,-0.324421437,-0.013196376,-0.066260707,0.183913655,1.849483527,713.1858109
331.076792,-1.162558574,-0.433037273,-0.0663472,0.124997633,0.190802973,1.804245949,714.5177539
334.8917384,0,0,0,0,0,0,0
338.7056061,0,0,0,0,0,0,0
342.5036806,0,0,0,0,0,0,0
346.3005682,0,0,0,0,0,0,0
350.1192409,0,0,0,0,0,0,0
353.9290192,0,0,0,0,0,0,0
357.7427786,0,0,0,0,0,0,0
361.5458578,0,0,0,0,0,0,0
365.361682,0,0,0,0,0,0,0
369.1383934,0,0,0,0,0,0,0
372.929237,0,0,0,0,0,0,0
376.725482,0,0,0,0,0,0,0
380.5381908,0,0,0,0,0,0,0
384.3440369,0,0,0,0,0,0,0
388.1447545,0,0,0,0,0,0,0
411.030062,0,0,0,0,0,0,0
414.8229182,0.908727957,0.64810911,0.111117338,-0.167809318,-0.07334771,0.647903329,1096.821391
418.6171341,0.809314214,0.226750747,-0.127919357,0.197161752,0.15923728,0.304986968,1906.900941
422.4302305,-0.002279147,-0.066761316,0.182487303,0.047367351,-0.069218159,0.296438074,3376.573877
426.2433376,-0.205813384,-0.597260617,-0.018375725,0.060834047,0.250626579,0.150239859,3251.716385
430.0408488,0.078022156,0.165489945,-0.068409455,-0.154563355,0.118488173,-0.135594991,2906.278617
433.8093483,0.190640426,-0.005215302,-0.025618272,0.11828923,-0.190545802,0.064739456,3599.321642
437.6019547,0.09504493,-0.060859996,-0.004786402,-0.010281343,-0.152637356,-0.223756751,3922.13398
441.4075306,-0.940518969,0.335330489,0.066147574,-0.257715067,-0.114286978,-0.455277954,4226.036088
445.1742669,-0.276302833,-1.113099959,-0.171346788,-0.176743424,-0.638416694,-0.459042538,4323.169624
448.9760837,-0.626900809,-0.246532318,0.006816016,-0.189091238,-0.50746578,-0.176634282,4070.981413
452.7575432,-0.242523284,-0.626069647,-0.192642699,-0.289375791,-0.899427658,-0.488942973,4077.287045
456.5877065,-0.868029969,-0.142698389,0.178189847,-0.519502818,-0.458455697,-0.369704933,4220.259352
460.367023,-0.743763769,-0.565589844,-0.062389716,-0.475298071,-0.667930176,-0.315321536,4285.637886
464.185266,-0.90776135,-0.492888332,-0.015557164,-1.164183577,-0.943730315,-0.246707916,4374.104528
467.9800892,-0.578497241,-1.03916112,-0.083991282,-0.22475653,-0.878018762,-0.555980209,4136.43271
471.7738184,-0.608664292,-0.593178433,-0.033820148,-0.634410578,-0.541737575,-0.711380648,4146.398951
475.5711092,-1.108150155,-0.756496627,9.84e-06,-0.504823259,-0.828129267,-0.539005836,4226.38244
479.389668,-0.895711887,-0.82202555,-0.010060126,-0.710449368,-0.905297525,-0.466668126,4231.292789
483.1942553,-0.462265305,-0.473951003,0.01317308,-0.623058957,-0.92686981,-0.482997315,4158.371517
487.0208441,-1.781498381,-0.416910843,-0.118171069,-0.736556276,-0.801366475,-0.823925347,4270.181084
490.8276582,-0.786690184,-0.44863351,0.174732474,-0.533133517,-0.646935558,-0.660253608,4140.582398
494.6275373,-1.004228584,-0.642368271,0.387021566,-0.705172045,-0.7308003,-0.778414504,4344.2179
498.4516659,14.20442619,3.418782315,0.722911945,5.923993358,7.004928003,-0.836211369,3827.496115
502.2404854,15.34146666,3.541587116,0.840891632,7.438000452,6.421913182,-0.655512252,4314.81123
506.058114,9.182256207,1.71772435,0.864357535,6.065931629,5.011351543,-0.772391799,6478.168761
509.8904253,12.33002514,2.351300479,0.97311928,6.544415979,5.540287038,-0.670418453,4480.842994
513.7130941,13.71657075,4.031615297,0.792151511,5.938912328,5.00282556,-0.342867337,3122.095269
517.5228086,13.2660071,3.760986705,1.035528734,5.832255262,5.34999777,0.025718265,2770.353976
521.3193785,12.67596557,3.341109149,1.070662878,5.207297951,4.716893799,0.293693797,2678.098789
525.1299922,13.77993373,3.035516157,0.972174859,5.273346706,5.162274721,0.37757369,2555.850256
528.9336753,14.46066116,4.199728553,1.28679874,6.034010094,5.432182289,0.567575263,2317.837124
532.7447232,14.20341753,4.086455302,0.955461537,5.803029484,5.571590101,0.777713302,2401.975516
536.548427,15.60321695,4.140260774,1.163853782,6.002998956,5.805215874,0.359536635,2364.591832
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